SPECTRUM CHEMICAL MFG CORP. -- FERROUS SULFATE HEPTAHYDRATE, F3240 -- 6810-003005157
===================== Product Identification ===================== Product ID:FERROUS SULFATE HEPTAHYDRATE, F3240 MSDS Date:09/26/1997 FSC:6810 NIIN:003005157 Status Code:A === Responsible Party === Company Name:SPECTRUM CHEMICAL MFG CORP. Address:14422 SOUTH SAN PEDRO STREET City:GARDENA State:CA ZIP:90248 Country:US Info Phone Num:310-516-8000 Emergency Phone Num:800-424-9300 Preparer's Name:E BRULL Chemtrec Ind/Phone:(800)424-9300 CAGE:63415 === Contractor Identification === Company Name:SPECTRUM LABORATORY PRODUCTS INC Address:14422 S SAN PEDRO ST Box:City:GARDENA State:CA ZIP:90248-2027 Country:US Phone:310-516-8000/FAX: 310-516-9843 CAGE:63415 ============= Composition/Information on Ingredients ============= Ingred Name:FERROUS SULFATE HEPTAHYDRATE CAS:7782-63-0 RTECS #:NO8510000 = Wt:100. EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 1480 MG/KG Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: VERY DANGEROUS IN CASE OF SKIN CONTACT(IRRITANT), OF EYE CONTACT(IRRITANT). VERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE OF INGESTION, OF INHALATION. THIS PRODUCT MAY IRRITATE EYES & SKIN UPON C ONTACT. INFLAMMATION OF EYE IS CHARACTERIZED BY REDNESS, WATERING, AND ITCHING. SKIN INFLAMMATION IS CHARACTERIZED BY ITCHING, SCALING, REDDENING, OR, OCCASIONALLY, BLISTERING. CHRONIC: VERY DANGEROUS IN CASE OF SKIN CONTACT(IRRITANT), OF EYE CONTACT(IRRITANT). VERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE OF INGESTION, OF INHALATION. CARCINOGENIC EFTS: NOT AVAILABLE. MUTAGENIC EFTS: NOT AVAIL. (EFT S OF OVEREXP) Effects of Overexposure:HLTH HAZS: TERATOGENIC EFTS: NOT AVAILABLE. THE SUBSTANCE IS TOXIC TO LUNGS, LIVER, TOX OF PROD TO THE REPRODUCTIVE SYSTEM: NOT AVAILABLE. RPTD OR PRLNGD EXPOSURE TO SUBSTANCE CAN PRODUCE TARGET ORGAN S DAMAGE. RPTD/PRLNGD INHAL OF DUST MAYLEAD TO CHRONIC RESP IRRIT. ======================= First Aid Measures ======================= First Aid:EYE CONT: CHECK FOR & REMOVE ANY CONTACT LENSES. IMMED FLUSH W/RUNNING WATER FOR @ LST 15 MINS, KEEPING EYELIDS OPEN. COLD WATER MAY BE USED. DO NOT USE EYE OINTMENT. SEEK MED ATTN. SKIN CONT: IF CHEM GOT ONTO CLOTHED PORTION OF BODY, REMOVE CONTAMD CLOTHES AS QUICKLY AS POSS, PROTECTING YOUR OWN HANDS & BODY. PLACE VICTIM UNDER DELUGE SHOWER. IF CHEM TOUCHES VICTIM'S EXPOSED SKIN, SUCH AS HANDS, NEUT EXPOSED SKIN W/DILUTE SOLN OF SODIUM CARBONATE. GENTLY & THOROUGHLY WASH CONTAMD SKIN W/RUNNING WATER & NON-ABRASIVE SOAP. (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:NON-FLAMMABLE. MEDIA SUITABLE FOR SURROUNDING FIRE . Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:RISKS OF EXPLOSION OF PROD IN PRESENCE OF MECH IMPACT: NOT AVAIL. RISKS OF EXPLOSION OF PROD IN PRESENCE OF STATIC DISCHARGE: NOT AVAIL. NO SPECIFIC INFO IS AVAILABLE IN DATABASE REGARDING PROD'S RISK S OF EXPLOSION IN PRESENCE OF VARIOUS MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:SM SPILL: USE APPROP TOOLS TO PUT SPILLED SOLID IN CONVENIENT WASTE DISP CNTNR. IF NEC: NEUT RESIDUE W/DILUTE SOLN OF SODIUM CARBONATE. FINISH CLEANING BY SPREADING WATER ON CONTAMD SURF & DISPOSE OF ACCORD TO LOC & REGIONAL AUTHORITY REQUIREMENTS. LG SPILL: USE SHOVEL TO PUT MATL INTO CONVENIENT WASTE DISP CNTNR. NEUT RESIDUE W/DILUTE SOLN OF SODIUM CARBONATE. Neutralizing Agent:NEUTRALIZE THE RESIDUE WITH A DILUTE SOLUTION OF SODIUM CARBONATE. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT INGEST. DO NOT BREATHE DUST. IF INGESTED, SEEK MEDICAL ADVICE IMMEDIATELY AND SHOW THE CONTAINER OR THE LABEL. AVOID CONTACT WITH SKIN AND EYES. KEEP AWAY FROM INCOMPATIBLES AS OXIDIZING AGENTS , REDUCING AGENTS, ACIDS, MOISTURE. Other Precautions:NO SPEICIFIC STORAGE IS REQD. USE SHELVES OR CABINETS STURDY ENOUGH TO BEAR THE WEIGHT OF THE CHEMICALS. BE SURE THAT IT IS NOT NECESSARY TO STRAIN TO REACH MATERIALS, AND THAT SHELVES ARE NOT OVERLOA DED. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE PROCESS ENCLOSURES, LOCAL EXHST VENT/OTHER ENGINEERING CTLS TO KEEP AIRBORNE LEVELS BELOW REC EXPOSURE LIMITS. IF USER OPERATIONS GENERATE DUST, FUME/MIST, USE VENT TO KEEP EXPOS TO AIRBORNE CONTA MINANTS BELOW EXPOS LIMIT. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LAB COAT. LG SPILL: SUGGESTED PROTECTIVE CLOTHING MIGHT NOT BE SUFFICIENT; CONSULT SPECIALIST BEFORE HNDLG PRODUCT. Supplemental Safety and Health FIRST AID PROC: BE PARTICULARLY CAREFUL TO CLEAN FOLDS, CREVICES, CREASES & GROIN. COLD WATER MAY BE USED. COVER IRRITATED SKIN W/EMOLLIENT. IF IRRIT PERSISTS, SEEK MED ATTN. WASH CONTAMD CLTHG BEFORE REUSING. SERIOUS SKIN CONT: WASH W/DISINFECTANT SOAP & COVER CONTAMD SKIN WITH (OTHER INFO) ================== Physical/Chemical Properties ================== Melt/Freeze Pt:=56.6C, 133.8F M.P/F.P Text:DECOMPOSES Vapor Pres:14.6 @ 20C pH:4(1%SOLN/WATER) Solubility in Water:SOL IN COLD WATER. Appearance and Odor:SOLID BLUE TO BLUE-GREEN. (LIGHT) ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SLIGHTLY REACTIVE TO REACTIVE WITH OXIDIZING AGENTS, REDUCING AGENTS, ACIDS, MOISTURE. =================== Toxicological Information =================== Toxicological Information:CHRONIC EFTS ON HUMANS:THE SUBSTANCE IS TOXIC TO LUNGS, LIVER. TOX OF PROD TO REPROD SYS: NOT AVAIL. OTHER TOXIC EFTS ON HUMANS: VERY DANGEROUS IN CASE OF SKIN CONT(IRRITANT), OF EYE CONT(IRRITANT). V ERY SLIGHTLY TO SLIGHTLY DANGEROUS IN CASE OF INGESTION, OF INHALTION. SPEC REMARKS ON TOX TO ANIMALS: NO ADDNL REMARK. SPEC REMARKS ON HUMANS: EXCRETED IN MATERNAL MILK IN ANIMAL. SPEC REMARKS ON OTH ER TOXIC EFTS IN HUMANS: NO ADDNL REMARK. ===================== Ecological Information ===================== Ecological:EXOTOXICITY: NOT AVAILABLE. BOD5 AND COD: NOT AVAILABLE. PRODS OF BIODEGRADATION: SOME METALLIC OXIDES. TOC OF PRODS OF BIODEGRADATION: PROD ARE MORE TOXIC. ==================== Disposal Considerations ==================== Waste Disposal Methods:RECYCLE TO PROCESS, IF POSSIBLE. CONSULT YOUR FEDERAL, STATE, LOCAL AND REGIONAL AUTHORITIES. =================== MSDS Transport Information =================== Transport Information:DOT CLASSIFICATION: NOT DOT CONTROLLED MATERIAL (UNITED STATES). IDENTIFICATION: NA9125 III. ===================== Regulatory Information ===================== SARA Title III Information:FOLLOWING PROD(S) ARE LISTED ON SARA 313: FERROUS SULFATE HEPTAHYDRATE. Federal Regulatory Information:FOLLOWING PROD(S) IS (ARE) LISTED BY CERCLA: FERROUS SULFATE HEPTAHYDRATE. OSHA HAZARDOUS BY DEFINITION OF HAZARD COMMUNICATION STD (29 CFR 1910.1200). WHMIS (CANADA): WHMIS CLASS D-2A: MATL CAUSING O THER TOXIC EFTS (VERY TOXIC). DSCL (EEC): R22-HARMFUL IF INGESTED. R42-MAY CAUSE SENSITIZATION BY INHALATION. R38/38-IRRITATING TO EYES & SKIN. State Regulatory Information:FOLLOWING PROD(S) IS (ARE) LISTED BY STATE OF MASSACHUSETTS & PENNSYLVANIA: FERROUS SULFATE HEPTAHYDRATE. WARNING PROD CNTNS CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER. CHEM INGRED(S) REQUIRIN G THIS WARNING: NONE. WARNING: PROD CNTNS CHEM KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CHEM INGRED(S) REQUIRING THIS WARNING: NONE. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.