SIGMA CHEMICAL CO -- M-XYLENE, 95672 -- 6810-00N069769
===================== Product Identification ===================== Product ID:M-XYLENE, 95672 MSDS Date:10/01/1994 FSC:6810 NIIN:00N069769 === Responsible Party === Company Name:SIGMA CHEMICAL CO Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Info Phone Num:314-771-5765 Emergency Phone Num:516-467-3535 CAGE:21076 === Contractor Identification === Company Name:SIGMA CHEMICAL COMPANY Address:3050 SPRUCE ST Box:14508 City:ST LOUIS State:MO ZIP:63178 Country:US Phone:314-771-5765 CAGE:21076 ============= Composition/Information on Ingredients ============= Ingred Name:M-XYLENE; (M-DIMETHYLBENZENE) (SARA 313) (CERCLA) CAS:108-38-3 RTECS #:ZE2275000 OSHA PEL:100 PPM ACGIH TLV:100 PPM;15O STEL EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50:(ORAL, RAT) 5 G/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR ABSORBED THRU SKIN. CAUSES SEVERE IRRIT. HIGH CONCS ARE EXTREMELY DESTRUCTIVE TO TISSUES OF MUCOUS MEMBRANES & UPPER RESP TRACT, EYES & SKIN. SYMPS OF EXPOS MAY INCLUDE BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HDCH, NAUS & VOMIT. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:EXPOS CAN CAUSE:NARCOTIC EFT. LUNG IRRIT, CHEST PAIN & EDEMA WHICH MAY BE FATAL. CNS DEPRESSION. DERMATITIS. GI DISTURBS. CHRONIC:DMG TO LIVER/KIDNEYS. BLOOD EFTS. MAY CAUSE REPRO DISORDERS. TARGET ORGAN(S):NERVES, LIVER, KIDNEYS.TARGET ORGAN DATA:EFTS ON FERTILITY (LITTER SIZE). SPECIFIC DEVEL (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS. ASSURE ADEQ FLUSHING BY SEPARATING EYELIDS W/FINGERS. SKIN:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAM CLT HG & SHOES. REMOVE & WASH CONTAM CLTHG PROMPTLY. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. INGEST:WASH OUT MOUTH W/WATER PROVIDED PERS IS CONSCIOUS.(SUPDAT) ===================== Fire Fighting Measures ===================== Flash Point:77.0F,25.0C Lower Limits:7% Upper Limits:1.1% Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER/APPROPRIATE FOAM. WATER MAY BE EFTIVE FOR COOLING, BUT MAY NOT EFT EXTINGUISHMENT. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . FLAMMABLE. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION & FLASH BACK. CONTAINER EXPLOSION MAY OCCUR UNDER FIRE CONDITIONS. FORMS EXPLOSIVE MIXTS IN AIR. ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT. WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS & HEAVY RUBBER GLOVES. COVER W/ACTIVATED CARBON ADSORBENT, TAKE UP & PLACE IN CLSD CNTNRS. TRANSPORT OUTDOORS. V ENTILATE AREA & WASH SPILL SITE AFTER MATL(SUPDAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. READILY ABSORBED THRU SKIN. SEVERE IRRITANT. Other Precautions:REPRO HAZ. KEEP TIGHTLY CLSD. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. STORE IN COOL, DRY PLACE. FLAMM. HARMFUL BY INHAL, IN CONT W/SKIN & IF SWALLOWED. IRRIT TO EYES, RESP SYS & SKIN. KEEP AWAY FROM S OURCES OF IGNITION. NO SMOKING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation:USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves:CHEMICAL-RESISTANT GLOVES. Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA . WEAR SUITABLE PROTECTIVE CLOTHING. USE(SUPDAT) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EFTS OF OVEREXP:ABNORMS (CRANIOFACIAL). FIRST AID PROC:CALL MD. SPILL PROC:PICKUP IS COMPLETE. EYE PROT:& FULL LENGTH FACESHIELD . OTHER PROT EQUIP:NONSPARKING TOOLS. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:>280F,>138C Vapor Pres:16 @ 37.7C Vapor Density:3.7 Spec Gravity:0.868 Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZING AGENTS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS MATERIAL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.