ASHLAND OIL CO -- ALCOHOL-ETHANOL -- 6810-00D002921
=====================  Product Identification  =====================

Product ID:ALCOHOL-ETHANOL
MSDS Date:09/12/1991
FSC:6810
NIIN:00D002921
=== Responsible Party ===
Company Name:ASHLAND OIL CO
Address:1409 WINCHESTER AVE
Box:391
City:ASHLAND
State:KY
ZIP:41114
Country:US
Info Phone Num:606-324-1133
Emergency Phone Num:606-324-1133
CAGE:81355
=== Contractor Identification ===
Company Name:ASHLAND INC
Address:1409 WINCHESTER AVE
Box:391
City:ASHLAND
State:KY
ZIP:41114
Country:US
Phone:800-622-6846
CAGE:81355
Company Name:ROLLINS OIL CO
Address:2420 W COUNTY RD C
Box:City:ROSEVILLE
State:MN
ZIP:55113-2531
Country:US
Phone:612-636-4807
CAGE:7W404

=============  Composition/Information on Ingredients  =============

Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 95%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9293

Ingred Name:ALIPHATIC PETROLEUM DISTILLATES
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM  (MFR)
ACGIH TLV:400 PPM (MFR)

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:TLV:ALIPHATIC PETROLEUM DISTIL. 400 PPM
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:NO
Reports of Carcinogenicity:NTP:NO    IARC:YES	 OSHA:NO
Health Hazards Acute and Chronic:ACUTE- HIGH VAPOR CONCENTRATIONS MAY
    CAUSE NASAL & RESPIRATORY IRRITATION. CAN CAUSE MODERATE EYE
    IRRITATION, REDNESS & TEARING. CAN CAUSE SLIGHT SKIN IRRITATION.
    INGESTION CAN CAUSE GASTROINTESTINAL  IRRITATION, NAUSEA, VOMITING
    & DIARRHEA. CHRONIC- MAY CAUSE LIVER ABNORMALITIES & EYE DAMAGE.
Explanation of Carcinogenicity:IARC HAS DETERMINED THAT CHRONIC
    EXPOSURE TO ETHANOL THROUGH DRINKING CAN CAUSE CANCER.
Effects of Overexposure:HIGH VAPOR CONCENTRATIONS MAY CAUSE NASAL &
    RESPIRATORY IRRITATION. CAN CAUSE MODERATE EYE IRRITATION, REDNESS
    & TEARING. CAN CAUSE SLIGHT SKIN IRRITATION. INGESTION CAN CAUSE
    GASTROINTESTINAL IRRITAT ION, NAUSEA, VOMITING & DIARRHEA.
    PROLONGED EXPOSURE MAY CAUSE LIVER ABNORMALITIES & EYE DAMAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
    DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY
    BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE/SKIN:IMMEDIATELY FLUSH
    WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN. INHALED:REMOVE TO
    FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. ORAL:IF CONSCIOUS, DRINK 2
    GLASSE S OF WATER & INDUCE VOMITING. CALL A PHYSICIAN/POISON
    CONTROL CENTER IMMEDIATELY.

=====================  Fire Fighting Measures  =====================

Flash Point:55.0F,12.8C
Lower Limits:3.3%
Extinguishing Media:USE CO2, ALCOHOL FOAM, DRY CHEMICAL OR WATER.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT & A
    FULL FACED SELF CONTAINED BREATHING APPARATUS/SUPPLIED-AIR
    RESPIRATOR.COOL FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
    CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
    CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.

==================  Accidental Release Measures  ==================

Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS.ELIMINATE ALL
    SOURCES OF IGNITION.USE EXPLOSION-PROOF TOOLS.SHUT OFF FUEL
    SOURCE.DIKE SPILL.PREVENT LIQUID FROM ENTERING
    SEWERS/WATERWAYS.RECOVER FREE LIQUID.ADD SAND,EARTH  OR OTHER
    ABSORBENT MATERIAL.TRANSFER TOCONTAINER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORAGE-STORE IN ACCORDANCE WITH
    NATIONAL FIRE PROTECTION ASSOCIATION REGULATIONS.KEEP CONTAINERS
    CLOSED.HANDLE IN WELL-VENTILATED AREA.
Other Precautions:"EMPTY" CONTAINERS RETAIN RESIDUE AND CAN BE
    DANGEROUS.DO NOT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND OR
    EXPOSE SUCH CONTAINERS TO HEAT,FLAME,SPARKS.THEY MAY EXPLODE AND
    CAUSE INJURY/DEATH.AVOID  REPEATED OR PROLONGED CONTACT WITH SKIN.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WHEN CONCENTRATIONS IN AIR MAY EXCEED THE
    PERMISSIBLE EXPOSURE LIMIT, AND WHERE ENGINEERING, WORK PRACTICES
    ARE NOT ADEQUATE, WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
    APPARATUS OR ORGANIC VAPOR RE SPIRATOR OR SUPPLIED-AIR RESPIRATOR.
Ventilation:LOCAL/MECHANICAL (GENERAL) VENTILATION - EXPLOSION PROOF,
    WELL GROUNDED EQUIPMENTS
Protective Gloves:RUBBER
Eye Protection:CHEMICAL SPLASH GOGGLES & FACE SHIELD
Other Protective Equipment:IMPERVIOUS CLOTHING TO AVOID SKIN AND EYE
    CONTACT. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH
    HANDS AFTER USING PRODUCT. AVOID BREATHING VAPORS OR MISTS.
Supplemental Safety and Health

==================  Physical/Chemical Properties  ==================

HCC:F3
Boiling Pt:B.P. Text:158F,70C
Vapor Pres:45 @ 68F
Vapor Density:>1
Spec Gravity:0.787 - 0.797
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR LIQUID - ALCOHOL ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, STATIC
    ELECTRICITY AND OTHER SOURCES OF IGNITION. PREVENT VAPORS
    ACCUMULATION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE

====================  Disposal Considerations  ====================

Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL
    MUST BE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
    LAWS AND REGULATIONS. RECOMMENDED PROCEDURE IS BY INCINERATION.

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