Material Safety Data Sheet
Barium chloride, anhydrous
ACC# 02370
Section 1 - Chemical Product and Company Identification |
MSDS Name: Barium chloride, anhydrous
Catalog Numbers:
AC612281000, B31-100C, B31-500
Synonyms:
Barium dichloride.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10361-37-2 |
Barium chloride |
> 97 | 233-788-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white solid.
Warning! Harmful if swallowed. Causes eye, skin,
and respiratory tract irritation. May cause lung damage. May cause
cardiac disturbances. May cause kidney damage.
Target Organs: Kidneys, heart, respiratory
system, muscles.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain. May cause
conjunctivitis.
Skin:
Causes skin irritation. Prolonged contact with the skin, especially
if the skin is wet or moist, causes necrosis.
Ingestion:
Harmful if swallowed. May cause kidney damage. The barium ion is a
muscle poison causing stimulation and then paralysis. Initial
symptoms are gastrointestinal, including nausea, vomiting, colic, and
diarrhea, followed by myocardial and general muscular stimulation
with tingling in the extremities.
Barium chloride affects the muscles (especially the smooth muscles of
the cardiovascular and respiratory systems), causes salivation,
tingling of the mouth or face, convulsions, numbness, muscle
paralysis, respiratory failure, slow pulse rate, pulmonary edema,
irregular heart beat, potassium deficiency in the
Inhalation:
Causes respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
Not available.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Do NOT use mouth-to-mouth resuscitation.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with
adequate ventilation. Minimize dust generation and accumulation.
Avoid contact with eyes, skin, and clothing. Do not ingest or
inhale.
Storage:
Store in a cool, dry place.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Barium chloride
|
0.5 mg/m3 TWA (listed under Barium).
|
0.5 mg/m3 TWA (as Ba) 50 mg/m3 IDLH
|
0.5 mg/m3 TWA (listed under Barium).
|
OSHA Vacated PELs:
Barium chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: Negligible.
Vapor Density: Not applicable.
Evaporation Rate:Negligible.
Viscosity: Not available.
Boiling Point: 1560 deg C
Freezing/Melting Point:960 deg C
Decomposition Temperature:Not available.
Solubility: 59% @ 100°C
Specific Gravity/Density:3.86
Molecular Formula:BaCl2
Molecular Weight:208.27
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Bromine trifluoride, Furan-2-peroxycarboxylic acid.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10361-37-2:
CQ8750000
LD50/LC50:
CAS# 10361-37-2:
Oral, mouse: LD50
= 150 mg/kg;
Oral, rat: LD50 = 118
mg/kg;
Oral, rat: LD50 = 397
mg/kg;
.
Carcinogenicity:
CAS# 10361-37-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
Barium chloride accumulates in plants when it exceeds calcium and
magnesium levels in soil.
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
BARIUM COMPOUNDS, N.O.S. |
BARIUM COMPOUNDS, N.O.S. (BARIUM CHLORIDE) |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN1564 |
UN1564 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10361-37-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10361-37-2: immediate, delayed.
Section 313
This material contains Barium
chloride (listed as Barium), > 97%, (CAS# 10361-37-2) which is
subject to the reporting requirements of Section 313 of SARA Title
III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10361-37-2 can be found on the
following state right to know lists: New Jersey, (listed as Barium),
Pennsylvania, (listed as Barium), Pennsylvania, (listed as Barium
compounds, n.o.s.), Massachusetts, (listed as Barium).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 25 Toxic if swallowed.
R 20 Harmful by inhalation.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 10361-37-2: 1
Canada - DSL/NDSL
CAS# 10361-37-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10361-37-2 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 12/12/1997
Revision #6 Date: 12/08/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.