WARDS NATURAL SCIENCE ESTABLISHMENT INC -- FERROUS SULFIDE (SEE SUPPL) -- -
===================== Product Identification ===================== Product ID:FERROUS SULFIDE (SEE SUPPL) MSDS Date:01/02/1992 FSC:NIIN:Submitter:D DG Status Code:A Kit Part:Y === Responsible Party === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Info Phone Num:(716) 359-2502 Emergency Phone Num:716-226-6177/716-334-4222 Resp. Party Other MSDS Num.:FF 210 Preparer's Name:ALEXANDER PICCARELLI Chemtrec Ind/Phone:(800)424-9300 CAGE:63759 === Contractor Identification === Company Name:WARDS NATURAL SCIENCE ESTABLISHMENT INC Address:5100 W HENRIETTA RD Box:92912 City:ROCHESTER State:NY ZIP:14692-9012 Country:US Phone:(716) 359-2502 Contract Num:MDA414-99-P-3705 CAGE:63759 ============= Composition/Information on Ingredients ============= Ingred Name:FERROUS SULFIDE CAS:1317-37-9 = Wt:100. ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY MANUFACTURER Health Hazards Acute and Chronic:IF FREE GASTRIC ACIDITY IS HIGH, THE INGESTION OF FERROUS SULFIDE MAY RESULT IN DECOMPOSITION TO HYDROGEN SULFIDE IN THE STOMACH, WITH SUBSEQUENT SYSTEMIC POISONING. CONTACT: SKIN CONTACT WITH FERROUS SULFIDE PRESENTS VERY LITTLE HAZARD. EYE CONTACT: PARTICULATE HAZARD ONLY. EXERCISE APPROPRIATE PROCEDURES TO MINIMIZE POTENTIAL HAZARDS. Explanation of Carcinogenicity:NO DATA PROVIDED BY MANUFACTURER Effects of Overexposure:IF FREE GASTRIC ACIDITY IS HIGH, THE INGESTION OF FERROUS SULFIDE MAY RESULT IN DECOMPOSITION TO HYDROGEN SULFIDE IN THE STOMACH, WITH SUBSEQUENT SYSTEMIC POISONING. CONTACT: SKIN CONTACT WITH FERROUS SULFIDE PRESENTS VERY LITTLE HAZARD. EYE CONTACT: PARTICULATE HAZARD ONLY. EXERCISE APPROPRIATE PROCEDURES TO MINIMIZE POTENTIAL HAZARDS. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY MANUFACTURER ======================= First Aid Measures ======================= First Aid:INGESTION: IF SWALLOWED, IF CONSCIOUS, GIVE ONE OR TWO GLASSES OF WATER TO DRINK. INDUCE VOMITING AND CALL PHYSICIAN IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYE: FLUSH WITH WATER. IF IRRITATION DEVELOPS OR PERSISTS, GET MEDICAL ATTENTION. SKIN: FLUSH THOROUGHLY WITH WATER. THEN WASH WITH MILD SOAP AND WATER. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY. IF SYM PTOMS OF ILLNESS DEVELOP, GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMMABLE Extinguishing Media:WATER SPRAY. Fire Fighting Procedures:IN FIRE CONDITIONS, WEAR NIOSH-APPROVED SELF0CONTAINED BREATHING APPARATUS; WEAR GOGGLES IF EYE PROTECTION IS NOT PROVIDED. Unusual Fire/Explosion Hazard:MODERATELY FLAMMABLE SOLID. YIELDS FLAMMABLE HYDROGEN SULFIDE ON CONTACT WITH ACIDS AND SULFUR DIOXIDE WHEN BURNING. FINELY DIVIDED FERROUS SULFIDE MAY FORM EXPLOSIVE MIXTURE IN AIR. HYDROGEN SULFIDE AND SULFUR DIOXIDE ARE BOTH EXTREMELY TOXIC GASES. ================== Accidental Release Measures ================== Spill Release Procedures:RECYCLE OR SWEEP UP WITH CARE, AVOID CONTACT WITH ACIDS, STRONG OXIDIZERS OR VERY HIGH TEMPERATURES. PLACE IN SUITABLE CONTAINER. WASH SPILL AREA WITH SOAP AND WATER. Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM ACIDS, ACID FUMES, STRONG OXIDIZERS OR FIRE HAZARDS. WASH THOROUGHLY AFTER HANDLING. USE WITH ADEQUATED VENTILATION. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. DO NOT DEPEND ON ODOR TO DETECT PRESENCE OF GAS. HYDROGEN SULFIDE GAS DEADENS THE SENSE OF SMELL. AVOID CONTACT WITH SKIN, EYES, AND MUCOUS MEMB RANES. DO NOT BREATHE DUST. PREMOVE AND WASH CONTAMINATED CLOTHING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL HANDLING OF FERROUS SULFIDE IN THE LABORATORY. IF CONTACT WITH ACIDS WORK IN FUME HOOD OR WEAR NIOSH-APPROVED SELF-CONTAINED RESPIRATOR. Ventilation:LOCAL/MECHANICAL (GENERAL): RECOMMENDED. Protective Gloves:RUBBER Eye Protection:CHEMICAL SAFETY GLASSES Other Protective Equipment:SMOCK, APRON, EYE WASH STATION, FUME HOOD, PROPER GLOVES. Work Hygienic Practices:NO DATA PROVIDED BY MANUFACTURER Supplemental Safety and Health AIR POLLUTION KIT P/N: 36W2045. HCC IS FOR KIT BASED ON TABLE 3, DLAI 4145.11. HCC FOR THIS PART: N1. RELATED KIT MSDS': CLJPM, CLJPP, CLJPR, CLJPT, CLJPV, CLJPX. ================== Physical/Chemical Properties ================== HCC:F8 Boiling Pt:B.P. Text:DECOMPOSES Melt/Freeze Pt:=1194.C, ######F Decomp Temp:Decomp Text:DECOMPOSES Vapor Pres:NEGLIGIBLE AS SOLID Vapor Density:N/D Spec Gravity:4.84 Evaporation Rate & Reference:NON-VOLITILE Solubility in Water:INSOLUBLE Appearance and Odor:BROWNISH-BLACK LUMPS, RODS OR GRANULAR POWDER; NO ODOR Percent Volatiles by Volume:NON-VOLITILE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES CONTACT WITH ACIDS LIBERATES HYDROGEN SULFIDE(H2S) A POISONOUS GAS, STRONG OXIDIZERS. Stability Condition to Avoid:ACIDS, HIGH HEAT. MOISTURE SENSITIVE. Hazardous Decomposition Products:YIELDS TOXIC SULFIDE GAS ON CONTACT WITH ACIDS AND TOXIC SULFUR DIOXIDE WHEN BURNING. =================== Toxicological Information =================== Toxicological Information:NO DATA PROVIDED BY MANUFACTURER ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY MANUFACTURER ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN AN APPROVED CHEMICAL LANDFILL OR CONTRACT WITH A LICENSED WASTE DISPOSAL SERVICE. =================== MSDS Transport Information =================== Transport Information:NON-REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY MANUFACTURER Federal Regulatory Information:NO DATA PROVIDED BY MANUFACTURER State Regulatory Information:NO DATA PROVIDED BY MANUFACTURER ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.