UNION OIL OF CALIFORNIA; UNION CHEMICAL DIV. -- HEXANE (N-HEXANE) (AMSCO SOLV 1487) -- 8040-00-853-8913
===================== Product Identification ===================== Product ID:HEXANE (N-HEXANE) (AMSCO SOLV 1487) MSDS Date:03/14/1990 FSC:8040 NIIN:00-853-8913 === Responsible Party === Company Name:UNION OIL OF CALIFORNIA; UNION CHEMICAL DIV. Address:1345 NORTH MEACHAM ROAD City:SCHAUMBURG State:IL ZIP:60195 Country:US Info Phone Num:714-864-2310 Emergency Phone Num:714-864-2310/ 800-424-9300 Preparer's Name:C. A. EISENHARD CAGE:IO438 === Contractor Identification === Company Name:CHEMICAL COMMODITIES AGENCY, INC. Address:27447 PACIFIC STREET Box:City:HIGHLAND State:CA ZIP:92346-2640 Country:US Phone:909-864-2310 CAGE:60777 Company Name:UNION OIL CO OF CALIFORNIA, CORP. DIV-EASTERN Address:1650 EAST GOLF ROAD Box:City:SCHAUMBURG State:IL ZIP:60195 Country:US Phone:708-619-2644 CAGE:77416 Company Name:UNION OIL OF CALIFORNIA Address:1201 WEST 5TH ST City:LOS ANGELES State:CA ZIP:90017 Country:US Phone:213-977-7589 CAGE:IO438 ============= Composition/Information on Ingredients ============= Ingred Name:HEXANE (N-HEXANE) CAS:110-54-3 RTECS #:MN9275000 Other REC Limits:NONE SPECIFIED OSHA PEL:500 PPM ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:CYCLOHEXANE CAS:110-82-7 RTECS #:GW9275000 Fraction by Wt: 0.3-0.9% Other REC Limits:NONE SPECIFIED ACGIH TLV:300 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:OTHER HEXANE ISOMERS Other REC Limits:NONE SPECIFIED ACGIH TLV:500 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:IRRITATION OF THE EYES, SKIN, NOSE & THROAT, DIGESTIVE SYS. EYE: DIRECT CONTACT MAY CAUSE STINGING, TEARING, REDNESS. SKIN: PROLONGED/REPEATED USE MAY CAUSE REDNESS, BURNING AND DRYING & CRACKING. SKI N ABSORPTION. INHALE/INGEST: NERVOUS SYS DEPRESSION. INHALE: PERIPHERAL NERVE DAMAGE. INGEST: NAUSEA. LUNG ASPIRATION. Effects of Overexposure:NERVOUS SYS DEPRESSION: HEADACHE, DROWSINESS, DIZZINESS, LOSS OF COORDINATION AND FATIGUE. ASPIRATION: MATERIAL ENTERS LUNGS WHEN SWALLOWING OR VOMITING & CAUSES LUNG INFLAMMATION & DAMAGE. REPORTS HA VE ASSOCIATED REPEATED/PROLONGED OCCUPATIONAL OVER-EXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISEASE IS MORE SUSCEPTIBLE TO EFFECTS OF THIS MATERIAL. LUNG DISORDERS MAY BE AGGRAVATED BY EXPOSURE. PRE-EXISTING HEART DISORDERS MAY BE MORE SUSCEPTIBLE TO IRREGULAR HEART BEATS. ======================= First Aid Measures ======================= First Aid:EYE: MOVE VICTIM TO FRESH AIR. DIRECT CONTACT: HOLD EYELIDS APART & FLUSH EYE W/CLEAN WATER. GET MEDICAL AID. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA THOROUGHLY W/MILD SOAP & WATER. GET MEDICAL AID. INHALE: MOVE VICTIM TO FRESH AIR. CPR OR OXYGEN AS NEEDED. IMMEDIATE MEDICAL AID. INGEST: DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL CAN ENTER LUNGS. GET MEDICAL AID. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:-20F,-29C Lower Limits:1.0 Upper Limits:8.0 Extinguishing Media:EXTINGUISH WITH DRY CHEMICAL, CO2 OR A UNIVERSAL TYPE FOAM. Fire Fighting Procedures:USE SCBA. WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPORS & COOLING CONTAINERS EXPOSED TO HEAT & FLAME. AVOID SPREADING BURNING LIQUID W/WATER USED FOR COOLING. Unusual Fire/Explosion Hazard:FLASHBACK ALONG VAPOR TRAIL MAY OCCUR. EXTREMELY FLAMMABLE & MAY IGNITE W/HEAT, SPARKS,FLAME OR STATIC ELEC. IF CONTAINER IS NOT PROPERLY COOLED IT MAY EXPLODE. ================== Accidental Release Measures ================== Spill Release Procedures:STAY UPWIND & AWAY FROM SPILL. KEEP IGNITION SOURCES AWAY. VENTILATE AREA. A UNIVERSAL TYPE FOAM MAY BE USED TO SUPPRESS VAPORS. KEEP OUT OF DRAINS, SEWERS OR WATERWAYS. USE INERT MATERIAL/ABSORBENT T O DAM, CONTAIN, MOP UP. DO NOT FLUSH AREA W/WATER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. KEEP COOL, DRY & AWAY FROM IGNITON SOURCES. USE W/ADEQUATE VENTING. DO NOT PRESSURIZE, CUT, WELD, BRAZE SOLDER,DRILL,* Other Precautions:*GRIND OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES IF IGNITION. "EMPTY" DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & PROMPTLY SHIPPED TO SUPPLIER OR DRUM RECONDITIONER. FOLLOW OSHA REGULATIONS, ANSI 149.1. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF AIRBORNE CONCENTRATIONS EXCEED ESTABLISHED EXPOSURE LIMITS USE A SUPPLIED AIR RESPIRATOR. DO NOT USE A CHEMICAL CARTRIDGE RESPIRATOR. Ventilation:ADEQUATE VENTILATION TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW THE ESTABLISHED LIMITS. Protective Gloves:IMPERMEABLE GLOVES TO PREVENT CONTACT. Eye Protection:APPR'D EYE PROTECTION TO PREVENT CONTACT Other Protective Equipment:SOURCE OF CLEAN WATER TO BE AVAILABLE IN WORK AREA FOR FLUSHING EYE/SKIN. IMPERVIOUS CLOTHING SHOULD BE WORN AS NEEDED. Supplemental Safety and Health ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:150 TO 158F Vapor Pres:140 @ 20C Vapor Density:> AIR Spec Gravity:0.674 Evaporation Rate & Reference:8.10 Solubility in Water:NEGLIGIBLE Appearance and Odor:CLEAR, LITTLE IF ANY COLOR, ODOR-CHARACTERISTIC Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES THIS PRODUCT IS INCOMPATIBLE WITH STRONG ACIDS OR BASES, OXIDIZING AGENTS AND SELECTED AMINES. Hazardous Decomposition Products:COMBUSTION MAY YIELD CARBON MONOXIDE AND/OR CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. DISPOSE IN AN ENVIRONMENTALLY SAFE MANNER. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.