DU PONT E I DE NEMOURS & CO INC -- "HYVAR" X-L HERBICIDE -- 6840-00-392-7593
===================== Product Identification ===================== Product ID:"HYVAR" X-L HERBICIDE MSDS Date:10/11/1996 FSC:6840 NIIN:00-392-7593 === Responsible Party === Company Name:DU PONT E I DE NEMOURS & CO INC Address:1007 MARKET STREET Box:1635 City:WILMINGTON State:DE ZIP:19898 Country:US Info Phone Num:800-441-7515/MSDS 302-992-3511 Emergency Phone Num:800-441-3637/800-424-9300(CHEMTREC) Preparer's Name:AGRICULTURAL PRODUCTS CAGE:18873 === Contractor Identification === Company Name:E.I. DUPONT DE NEMOURS & CO Address:1007 MARKET STREET Box:City:WILMINGTON State:DE ZIP:19898 Country:US Phone:800-441-7515;800-441-9442 CAGE:18873 Company Name:SUMMIT HELICOPTER Box:UNKNOW CAGE:0Y0Z8 Company Name:TIMBERLAND ENTERPRISES INC Address:140 ARKANSAS ST Box:557 City:MONTICELLO State:AR ZIP:71655 Country:US Phone:501-367-8561 CAGE:1HB45 ============= Composition/Information on Ingredients ============= Ingred Name:BROMACIL (LITHIUM SALT OF 5-BROMO-3-SEC-BUTYL-6-METHYLURACIL) CAS:314-40-9 RTECS #:YQ9100000 Fraction by Wt: 21.9% Other REC Limits:NONE RECOMMENDED OSHA PEL:1 PPM ACGIH TLV:10 MG/M3; 9596 Ingred Name:INERT INGREDIENTS, INCLUDES % OF THE FOLLOWING INGREDS (3,4,5) Fraction by Wt: 78.1% Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 30-35% Other REC Limits:NONE RECOMMENDED ACGIH TLV:C STEL39PPM,A4,VAP96 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:ETHYL ALCOHOL (ETHANOL) CAS:64-17-5 RTECS #:KQ6300000 Fraction by Wt: <10% Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:1000 PPM; 9596 Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA) CAS:67-56-1 RTECS #:PC1400000 Fraction by Wt: <5% Other REC Limits:NONE RECOMMENDED OSHA PEL:S, 200 PPM ACGIH TLV:S,200PPM/250STEL; 96 EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RAT) IS 2000 MG/KG Routes of Entry: Inhalation:NO Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:WARNING! HARMFUL OR FATAL IF SWALLOWED. CAUSES EYE IRRITATION. MAY IRRITATE NOSE, THROAT AND SKIN. Explanation of Carcinogenicity:NOT CARCINOGENIC. Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INHALATION-REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS HARD, GIVE OXYGEN. CALL A PHYSICIAN. SKIN-IMMEDIATELY WASH SKIN WITH SOAP & WATER. EYE-IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR 15 MIN. CALL A PHYSICIAN. INGESTION-IMMEDIATELY GIVE 2 GLASSES OF WATER & INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:SCC Flash Point:111F,44C Autoignition Temp:Autoignition Temp Text:770F Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE. Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WEAR FULL PROTECTIVE EQUIPMENT. USE WATER SPRAY. COOL TANK/CONTAINER WITH WATER SPRAY. RUNOFF FIRE POLLUTION HAZARD. Unusual Fire/Explosion Hazard:IF AREA IS HEAVILY EXPOSED TO FIRE AND IF CONDITIONS PERMIT, LET FIRE BURN ITSELF OUT SINCE WATER MAY INCREASE THE AREA CONTAMINATED. ================== Accidental Release Measures ================== Spill Release Procedures:DIKE SPILL. PREVENT MATERIAL FROM ENTERING SEWERS, WATERWAYS OR LOW AREAS. SOAK UP SAWDUST, SAND, OIL DRY OR OTHER ABSORBENT MATERIAL. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND FLAMES. STORE IN A WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. DO NOT STORE OR CONSUME FOOD, DRINK IN AREA. Other Precautions:DO NOT GET IN EYES. AVOID BREATHING VAPOR OR MIST. AVOID CONTACT WITH SKIN. AVOID CONTACT WITH CLOTHING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WHERE THERE'S POTENTIAL FOR AIRBORNE EXPO IN EXCESS OF APPLICABLE LIMITS WEAR NIOSH/MSHA APPROVED RESPIRATORY PROTECTION. Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY CLOSED. Protective Gloves:WEAR GLOVES. Eye Protection:SAFETY GLASSES. CHEMICAL SPLASH GOGGLES. Other Protective Equipment:WEAR APRON, BOOTS, COVERALLS. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health PH:11.2-12.2. FIREFIGHT:CONDITIONS PERMIT LET FIRE BURN ITSELF OUT SINCE WATER MAY INCR AREA CONTAMIN. DISPO IF ALLOWED BY STATE/LOC AUTHORITIES BURN.SARA/CERCLA RQ:METHYL ALCOHOL 5000LBS. OTHER PROT EQPT:WEAR APPROPRIATE IMPERVIOUS CLOTH,APRON,BOOTS,COVERALLS. ================== Physical/Chemical Properties ================== HCC:F4 Boiling Pt:B.P. Text:NP Melt/Freeze Pt:M.P/F.P Text:NP Decomp Temp:Decomp Text:NP Vapor Pres:NP Vapor Density:NP Spec Gravity:NP pH:SUPPLE Evaporation Rate & Reference:NP Solubility in Water:SOLUBLE. Appearance and Odor:LIQUID, AMBER COLOR, ALCOHOLIC ODOR. Percent Volatiles by Volume:NP Corrosion Rate:NP ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES INCOMPATIBLE WITH ACIDS AND AMINES, ESPECIALLY PRIMARY AMINES. Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AMD STORAGE CONDITIONS. Hazardous Decomposition Products:DECOMPOSES WITH HEAT. Conditions to Avoid Polymerization:WILL NOT OCCUR. ==================== Disposal Considerations ==================== Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTEM. 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