SUN REFINING AND MARKETING COMPANY -- TOLUENE -- 6810-00-579-8431
===================== Product Identification ===================== Product ID:TOLUENE MSDS Date:04/05/1989 FSC:6810 NIIN:00-579-8431 === Responsible Party === Company Name:SUN REFINING AND MARKETING COMPANY Address:TEN PENN CENTER 1801 MARKET STREET City:PHILADELPHIA State:PA ZIP:19103-1699 Country:US Info Phone Num:215-293-9270 (1631-0759) Emergency Phone Num:215-977-6172 (0800-1630) Preparer's Name:RAMONA PANSON CAGE:3T335 === Contractor Identification === Company Name:SUN COMPANY INC Address:1801 MARKET STREET Box:City:PHILADELPHIA State:PA ZIP:19103-1699 Country:US Phone:800-964-8861 CAGE:78628 Company Name:SUN REFINING AND MARKETING CO Address:676 E SWEDESFORD RD City:WAYNE State:PA ZIP:19087-1612 Country:US CAGE:3T335 ============= Composition/Information on Ingredients ============= Ingred Name:TOLUENE (SARA III) CAS:108-88-3 RTECS #:XS5250000 Fraction by Wt: 99%+% OSHA PEL:200 PPM/150 STEL ACGIH TLV:50 PPM; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA III) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: <1% OSHA PEL:1PPM/5STEL;1910.1028 ACGIH TLV:10 PPM; A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 5 GM/KG Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INGEST- PULMONARY ASPIRATION HAZARD IF SWALLOWED AND VOMITING OCCURS. EYE- CONTACT MAY CAUSE MODERATE TO SEVERE IRRITATION. INHALE- IRRITATION TO EYES, NOSE, CNS. CHRONIC: INHALE- REPEATED EXCE SSIVE EXPOSURES MAY CAUSE CHRONIC, ADVERSE SYSTEMIC EFFECTS. SKIN- MODERATE IRRITATION AND DEFATTING. Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN. Effects of Overexposure:DIZZINESS, LOSS OF BLANCE AND COORDITATION, UNCONSCIOUSNESS, COMA, RESPIRATORY FAILURE AND DEATH. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:48.0F,8.9C Autoignition Temp:Autoignition Temp Text:997F Lower Limits:1.2 Upper Limits:7.1 Extinguishing Media:USE CARBON DIOXIDE, CHEMICAL FOAM, WATER FOG, SAND/DIRT. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID (FLASH POINT LESS THAN 100F). ================== Accidental Release Measures ================== Spill Release Procedures:PROEVENT IGNITION, STOP LEAK, VENTILATE AREA. CONTAIN SPILL. USE WATER SPRAY TO DISPERSE VAPORS. KEEP UPWIND OF LEAK. WEAR SCBA FOR LARGE SPILL. ADVISE EPA; STATE AGENCY IF REQUIRED. ABSORB ON INERT M ATERIAL. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE ONLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE AND DUST/MIST PRE-FILTER RESPIRATORS AS PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/ WARNINGS AND NIOSH-RESPIRATOR SELECTION. Ventilation:MECHANICAL (GENERAL) ROOM VENTILATION IS NORMALLY ADEQUATE. LOCAL EXHAUST MAY BE REQUIRED IF WORK AREA NOT VENTED. Protective Gloves:IMPERVIOUS Eye Protection:SAFETY GOGGLES WITH OPTIONAL FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER. WEAR IMPERVIOUS PROTECTIVE GEAR. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=110.6C, 231.F Melt/Freeze Pt:=-95.C, -139.F Vapor Pres:26 Vapor Density:3.2 Spec Gravity:0.87 Evaporation Rate & Reference:(ETHYL ETHER=1) 5X SLOWER Solubility in Water:0.047 % BY VOL. Appearance and Odor:COLORLESS LIQUID WITH PLEASANT SWEET ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE AND ASPHYXIANTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. DO NOT FLUSH TO DRAIN/STORM SEWER. INCINERATE UNDER CONTROLLED CONDITIONS. DRAIN TO CHEMICAL WA STE PLANT. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.