DOW CHEMICAL USA -- DOWTHERM SR-1 40 HEAT TRANSFER FLUID 20889 -- 6850-00N017282
===================== Product Identification ===================== Product ID:DOWTHERM SR-1 40 HEAT TRANSFER FLUID 20889 MSDS Date:03/12/1990 FSC:6850 NIIN:00N017282 === Responsible Party === Company Name:DOW CHEMICAL USA Address:2020 DOW CENTER City:MIDLAND State:MI ZIP:48674 Country:US Info Phone Num:517-636-4400 Emergency Phone Num:517-636-4400 CAGE:EO044 === Contractor Identification === Company Name:DOW CHEMICAL CO Address:100 LARKIN CENTER Box:City:MIDLAND State:MI ZIP:48674 Country:US Phone:800-258-2436 CAGE:96717 Company Name:DOW CHEMICAL USA Address:2020 DOW CENTER City:MIDLAND State:MI ZIP:48640-6030 Country:US CAGE:EO044 ============= Composition/Information on Ingredients ============= Ingred Name:ING 5: MAY CAUSE IRRITATION TO UPPER RESP TRACT. OBSERVATIONS IN ANIMALS INCLUDE FORMATION OF BLADDER STONES (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: AFTER RPTD ORAL DOSES OF DIETHYLENE GLYCOL. OBSERVATIONS IN ANIMALS INCLUDE KIDNEY & LIVER EFTS & (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: DEPOSITION OF CALCIUM SALTS IN VARIOUS TISSUES AFTER LONG-TERM DIETARY INTAKE OF ETHYLENE GLYCOL. BASED (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:ON DATA FROM LONG-TERM ANIMAL STUDIES, DIETHYLENE GLYCOL IS NOT BELIEVED TO POSE CARCINOGENIC RISK TO MAN.(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: ETHYLENE GLYCOL DID NOT CAUSE CANCER IN LONG-TERM ANIMALS STUDIES BASED ON ANIMAL STUDIES INGEST OF VERY(ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: LRG AMTS OF ETHYLENE GLYCOL APPEARS TO BE THE MAJOR & POSS ONLY ROUTE OF EXP TO PRODUCE BIRTH DEFECTS. (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: EXP BY INHAL/SKIN CONTACT, THE PRIMARY ROUTES OF OCCUP EXP, HAD MINIMAL/ESSENTIALLY NO EFT ON THE FETUS(ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: BIRTH DEFECTS ARE UNLIKELY FROM EXP TO DIETHYLENE GLYCOL. EXP HAVING NO ADVERSE EFTS ON THE MOTHER (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: SHOULD HAVE NO EFTS ON THE FETUS. DIETHYLENE GLYCOL HAS NOT INTERFERED W/REPRODUCTION IN ANIMAL STUDIES.(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: IN STUDIES ON RATS, ETHYLENE GLYCOL HAS BEEN SHOWN NOT TO INTERFERE W/REPRODUCTION. IN STUDIES ON MICE, (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: INGEST OF EG IN LRG AMTS CAUSED A SML DECREASE IN NUMBER OF LITTERS/PAIR, LIVE PUPS/LITTER, IN LIVE (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: PUP WEIGHT. RESULTS OF INVITRO ('TEST TUBE') MUTAGENCITIY TESTS HAVE BEEN NEGATIVE. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: BE CONSIDERED. N ENG J MED 304:21 1981. IF BURN IS PRESENT, TREAT AS ANY THERMAL BURN AFTER (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: DECONTAM. CONSULT STANDARD LITERATURE. SUPPORTIVE CARE. TRTMT BASED ON JUDGMENT OF MD IN RESPONSE TO PATIENT. RTECS #:9999999ZZ Ingred Name:ETHYLENE GLYCOL CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: 40-43% OSHA PEL:50 PPM, C ACGIH TLV:50 PPM, C, VAPOR EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:DIETHYLENE GLYCOL CAS:111-46-6 RTECS #:ID5950000 Fraction by Wt: < 5% Ingred Name:DIPOTASSIUM PHOSPHATE CAS:7758-11-4 Fraction by Wt: < 5% Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: < 60% Ingred Name:SUPP DATA: BE ATTAINED THAT ARE SUFFICIENT TO CAUSE IRRIT AND OTHER EFTS. SYSTEMIC & OTHER EFTS: EXCESSIVE EXP (ING 6) RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL,RAT) 8200 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:EYE: ESSENTIALLY NONIRRIT. VAP/MISTS MAY BE IRRIT. SKIN: PRLNG/RPTD EXP NOT LIKELY TO CAUSE SIGNIFICANT SKIN IRRIT. MAY CAUSE MORE SEVERE RESPONSE IF SKIN IS ABRADED (SCRATCHED/CUT). SKIN ABSORP: A SI NGLE PRLNG EXP IS NOT LIKELY TO RESULT IN THE MATL BEING ABSORBED THROUGH SKIN IN HARMFUL AMTS. THE (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: DERMAL LD50 HAS NOT BEEN DETERMINED. RPTD SKIN EXP TO LRG QTYS MAY RESULT IN ABSORP OF HARMFUL AMTS. INGEST: EXCESSIVE EXP MAY CAUSE CNS EFTS, & KIDNEY FAILURE. IN DOWTHERM (R) SR-1 WHICH CN TNS 95 % ETHYLENE GLYCOL. SINGLE DOSE ORAL TOX IS EXPECTED MODERATE IN HUMANS EVEN THOUGH TESTS W/ANIMALS (SUPP DATA) Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: IRRIGATE IMMED W/H*2O FOR AT LEAST 15 MIN. SKIN: WASH OFF IN FLOWING H*2O/SHOWER. WASH CONTAM CLTHG BEFORE REUSE. INGEST: IF SWALLOWED, INDUCE VOMIT IMMED AS DIRECTED BY MED PERSONNEL. NEVER GIV E ANYTHING BY MOUTH TO AN UNCON PERSON.INHAL: REMOVE TO FRESH AIR IF EFTS OCCUR, SEE MD. NOTE TO MD: IN TRTMT OF INTOX, THE USE OF ETHANOL, HEMODIALYSIS & IV FLUIDS TO CONTROL ACIDOSIS SHOULD(ING 18) ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:NONE TO 220 F Extinguishing Media:WATER FOG, ALCOHOL FOAM AND DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE-PRESSURE, SCBA. Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER. ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS: SOAK UP WITH ABSORBENT MATERIAL. LARGE SPILLS: DIKE AND PUMP INTO SUITABLE CONTAINERS. CLEAN UP RESIDUAL WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID SKIN AND EYE CONTACT. DO NOT INGEST. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN OPERATIONS, USE A NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR. Ventilation:GOOD GENERAL VENTIALTION SHOULD BE SUFFICIENT FOR MOST CONDITIONS. LOCAL EXHAUST VENT MAY BE NEC FOR SOME OPERATIONS. Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:CHEMICAL WORKERS GOGGLES . Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP: SHOW A LOWER DEGREE OF TOX. AMTS INGESTED INCIDENTAL TO INDUS HANDLING ARE NOT LIKELY TO CAUSE INJURY: HOWEVER INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJURY, EVEN DEATH. INHA L: AT ROOM TEMP, VAP ARE MINIMAL DUE TOLOW VAP PRESS. IF HEATED/SPRAYED AS AN AEROSOL CONCENTRATIONS MAY (ING 5) ================== Physical/Chemical Properties ================== HCC:N1 Boiling Pt:B.P. Text:223F,106C Vapor Pres:17 @ 20 C Vapor Density:> 1 Spec Gravity:1.06 Solubility in Water:COMPLETE Appearance and Odor:PINK LIQUID, PUNGENT ODOR. ================= Stability and Reactivity Data ================= OXIDIZING MATERIALS. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER. ==================== Disposal Considerations ==================== Waste Disposal Methods:SALVAGE, OR BURN IN ACCORDANCE WITH APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.