PRAXAIR INC -- AIR -- 6830-00N060973
===================== Product Identification ===================== Product ID:AIR MSDS Date:10/01/1997 FSC:6830 NIIN:00N060973 Status Code:A === Responsible Party === Company Name:PRAXAIR INC Address:39 OLD RIDGEBURY RD City:DANBURY State:CT ZIP:06810-5113 Country:US Info Phone Num:800-772-9247 Emergency Phone Num:800-645-4633;800-424-9300(CHEMTREC) CAGE:0LV01 === Contractor Identification === Company Name:PRAXAIR, INC. Address:39 OLD RIDGEBURY RD Box:City:DANBURY State:CT ZIP:06810-5113 Country:US Phone:800-772-9247; 800-PRAXAIR CAGE:0LV01 ============= Composition/Information on Ingredients ============= Ingred Name:OXYGEN; % (WT): 19.5-23.5 CAS:7782-44-7 RTECS #:RS2060000 Fraction by Wt: >19.5% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:NITROGEN. % (WT): 76.5-80.5 CAS:7727-37-9 RTECS #:QW9700000 Fraction by Wt: >76.5% OSHA PEL:N/K ACGIH TLV:ASPHYXIANT; 9495 Ingred Name:SUPDAT: SUBJECTED TO A TEMP HIGHER THAN 125F (52C). CYLINDER HAS A PRESSURE RELIEF DEVICE DESIGNED TO VENT (ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: CONTENTS AT ELEVATED TEMPERATURES AND PRESSURE. RTECS #:9999999ZZ Ingred Name:OTHER PREC: DO NOT DRAG, ROLL, SLIDE/DROP. NEVER ATTEMPT TO LIFT A CYL BY ITS CAP, CAP IS INTENDED SOLELY TO (ING 6) RTECS #:9999999ZZ Ingred Name:ING 5: PROT THE VALVE. NEVER INSERT AN OBJECT (EG., WRENCH, SCREWDRIVER, PRY BAR) INTO CAP OPENINGS; DOING SO (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: MAY DMG VALVE & CAUSE A LEAK. USE AN ADJUSTABLE STRAP WRENCH TO REMOVE OVER-TIGHT/RUSTED CAPS. OPEN (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: VALVE SLOWLY IF VALVE IS HARD TO OPEN, DISCONTINUE USE & CNTCT YOUR SUPPLIER. USE IN UNDERWATER (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8: BREATHING: SUITABILITY OF THIS PROD FOR USE IN UNDERWATER BREATHING MUST BE DETERM BY/UNDER SUPERVISION (ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: OF SOMEONE EXPERIENCED IN USE OF UNDERWATER BREATHING GAS MIXS. THIS PERS MUST BE FAMILIAR W/HOW PROD (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: IS USED; FREQUENCY, DURATION, & EFTS OF USE; HAZ & SIDE EFTS OF USE, & PRECS TO TAKE TO AVOID/CONTROL (ING 12) RTECS #:9999999ZZ Ingred Name:ING 11: THEM. STORE & USE AWAY FROM FLAMM MATLS. NEVER LUBRICATE AIR VALVES, REGULATORS, ETC., W/ANY COMBUST (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: SUBSTANCE. ADDNL SAFETY & HLTH HAZ: HIGH-PRESSURE GAS. USE PIPING & EQUIP ADEQUATELY DESIGNED TO (ING 14) RTECS #:9999999ZZ Ingred Name:ING 13: W/STAND PRESSURES TO BE ENCOUNTERED. CLOSE VALVE AFTER EACH USE; KEEP CLSD EVEN WHEN EMPTY. PVNT REVERSE(ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: FLOW. REVERSE FLOW INTO CYL MAY CAUSE RUPTURE. USE A CHECK VALVE/OTHER PROT DEVICE IN ANY LINE/PIPING (ING 16) RTECS #:9999999ZZ Ingred Name:ING 15: FROM CYL. DO NOT STRIKE AN ARC ON CYL. DEFECT PRODUCED BY AN ARC BURN COULD LEAD TO CYL. (ING 17) RTECS #:9999999ZZ Ingred Name:ING 16: RUPTURE. NEVER WORK ON A PRESSURIZED SYS. IF THERE IS A LEAK, CLOSE THE CYL VALVE. BLOW SYS (ING 18) RTECS #:9999999ZZ Ingred Name:ING 17: DOWN IN A SAFE & ENVIRONMENTALLY SOUND MANNER IN COMPLIANCE W/ALL FED, STATE & LOCAL LAWS, THEN REPAIR (ING 19) RTECS #:9999999ZZ Ingred Name:ING 18: THE LEAK. NEVER GROUND A COMPRESSED GAS CYLINDER OR ALLOW IT TO BECOME PART OF AN ELECTRICAL CIRCUIT. RTECS #:9999999ZZ Ingred Name:CNDTNS (STAB): SAFETY INFO FOR EACH COMPONENT BEFORE YOU PRODUCT THE MIXTURE. CONSULT AN INDUSTRIAL HYGIENIST, (ING 21) RTECS #:9999999ZZ Ingred Name:ING 20: OR OTHER TRAINED PERSON WHEN YOU EVALUATE THE END PRODUCT. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: ASSISTANCE. DO NOT ATTEMPT TO DISPOSE OF RESIDUAL/UNUSED QUANTITIES. RETURN CYLINDER TO (ING 23) RTECS #:9999999ZZ Ingred Name:ING 22: SUPPLIER. FOR EMERGENCY DISPOSAL, SECURE CYLINDER, THEN SLOWLY DISCHARGE GAS TO THE ATMOSPHERE. RTECS #:9999999ZZ Ingred Name:OTHER PROT EQUIP: IN ACCORDANCE WITH OSHA 29 CFR 1910.132 AND 1910.133. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION, SKIN CONTACT, INGESTION, & EYE CONTACT: NO HARM EXPECTED. INGESTION: THIS PRODUCT IS A GAS AT NORMAL TEMPERATURE AND PRESSURE. BE SURE TO READ & UNDERSTAND ALL LABELS AND INSTRUCTIO NS SUPPLIED WITH ALL CONTAINERS OF THISPRODUCT. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NONE KNOWN. ======================= First Aid Measures ======================= First Aid:INGEST: NO EMERGENCY CARE ANTICIPATED. CALL MD IMMEDIATELY . INHAL: NO EMERGENCY CARE ANTICIPATED. REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES: NO EMERGENCY CARE ANT ICIPATED. IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD . SKIN: NO EMERGENCY CARE ANTICIPATED. FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . ===================== Fire Fighting Measures ===================== Extinguishing Media:OXIDIZING AGENT. MAY ACCELERATE COMBUSTION. USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . CAUTION! HIGH-PRESS GAS. EVACULATE ALL PERS FROM DANGER AREA. IMMED DELUGE CYLS W/H*2O FROM MAX (SUPDAT) Unusual Fire/Explosion Hazard:OXIDIZING AGENT. MAY ACCELERATE COMBUSTION. CNTCT W/FLAMM MATLS MAY CAUSE FIRE/EXPLOSION HEAT OF FIRE CAN BUILD PRESS IN CYL & CAUSE IT TO RUPTURE. (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:CAUTION! HIGH-PRESSURE GAS. SHUT OFF FLOW IF WITHOUT RISK. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE & USE W/ADEQUATE VENT. FIRMLY SECURE CYL UPRIGHT TO KEEP THEM FROM FALLING/BEING KNOCKED OVER. SCREW VALVE PROT CAP FIRMLY IN PLACE BY HAND. Other Precautions:STORE ONLY WHERE TEMP WILL NOT EXCEED 125F (52C). STORE FULL & EMPTY CYLS SEPARATELY. USE FIRST-IN, FIRST-OUT INVENTORY SYS TO PVNT STORING FULL CYLS FOR LONG PERIODS. PROTECT CYLS FROM DMG. USE SUITA BLE HAND TRUCK TO MOVE CYLS; (ING 5) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NOT REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN . Ventilation:LOCAL EXHAUST- NOT APPLICABLE. MECHANICAL (GENERAL)-ADEQUATE. SPECIAL-NOT APPLICABLE. OTHERS-NOT APPLICABLE. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS . Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER . METATARSAL SHOES FOR CYLINDER HANDLING. SELECT (ING 24) Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health BP: -318F,-194C. SPEC GRAV (AIR=1): AT 70F (21.1C) AND 1 ATM: 1.00. SOL IN H*2O: % BY WT:, VOL/VOL AT 32 F (0C): 0.0292. FIRE FIGHT PROC: DISTANCE UNTIL COOL, THEN MOVE THEM AWAY FROM FIRE AREA IF W/O UT RISK. ON-SITE FIRE BRIGADES MUST COMPLY W/OSHA 29 CFR 1910 156. EXPLO HAZ: NO PART OF CYL SHOULD BE (ING 3) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:SUPDAT Spec Gravity:SUPDAT Solubility in Water:SUPDAT Appearance and Odor:COLORLESS, ODORLESS, TASTELESS GAS AT NORMAL TEMPERATURE AND PRESSURE. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES FLAMMABLE AND COMBUSTIBLE MATERIALS. Stability Condition to Avoid:WHEN YOU MIX TWO/MORE GASES/LIQUEFIED GASES, YOU CAN CREATE ADDITIONAL, UNEXPECTED HAZS. OBTAIN & EVALUATE (ING 20) Hazardous Decomposition Products:NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:PVNT WASTE FROM CONTAMINATING SURROUND ENVIRONMENT. KEEP PERS AWAY. DISCARD ANY PROD, RESIDUE, DISPOSABLE CNTNR/LINER IN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE W/FED, STATE & LOCAL REGS . IF NEC, CALL YOUR LOCAL SUPPLIER FOR (ING 22) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.