EM SCIENCE -- ETHYL ETHER, DIETHYL ETHER, ETHYL OXIDE, EX0184 -- 6810-00N061079
===================== Product Identification ===================== Product ID:ETHYL ETHER, DIETHYL ETHER, ETHYL OXIDE, EX0184 MSDS Date:04/16/1993 FSC:6810 NIIN:00N061079 === Responsible Party === Company Name:EM SCIENCE Address:480 DEMOCRAT RD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Info Phone Num:609-354-9200 Emergency Phone Num:800-424-9300 (CHEMTREC) CAGE:DO242 === Contractor Identification === Company Name:E M SCIENCE DIV OF E M INDUSTRIES INC Address:480 DEMOCRAT ROAD Box:70 City:GIBBSTOWN State:NJ ZIP:08027 Country:US Phone:800-222-0342/609-423-6300 CAGE:63612 Company Name:EM SCIENCE Address:480 DEMOCRAT RD City:GIBBSTOWN State:NJ ZIP:08927 Phone:800-424-9300 (CHEMTREC) CAGE:DO242 ============= Composition/Information on Ingredients ============= Ingred Name:ETHANE, 1,1'-OXYBIS-; (ETHER) (CERCLA) CAS:60-29-7 RTECS #:KI5775000 Fraction by Wt: 100% OSHA PEL:400 PPM ACGIH TLV:400PPM/500STEL EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:P-CRESOL- 2,6-DI-TERT-BUTYL-; (2,6-DI-TERT-BUTYL-P-CRESOL) (% WT: 1PPM) CAS:128-37-0 RTECS #:GO7875000 Fraction by Wt: <0.1% OSHA PEL:10 MG/M3 ACGIH TLV:10 MG/M3 Ingred Name:RESP PROT: CNDTNS (SEE YOUR SFTY EQUIP SUPP). ENGINEERING &/ADMINISTRATIVE CTLS SHOULD BE IMPLEMENTED TO REDUCE EXPOS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 1215 MG/KG. Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED/SWALLOWED. IRRIT ON CONT W/SKIN, EYES/MUC MEMB. DEPRESSANT OF CNS & CAPABLE OF PRODUCING INTOXICATION, DROW, STUPOR & UNCON. DEATH DUE TO RESP FAILURE MAY RSLT FROM SEV & CON TINUED EXPOS. CHRONIC: NONE SPECIFIED BY MANUFACTURER. Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:PREEXISTING SKIN DISORDERS, EYE PROBLEMS OR IMPAIRED KIDNEY, LIVER OR RESPIRATORY FUNCTIONS. ALCOHOLIC BEVERAGE CONSUMPTION CAN ENHANCE THE TOXIC EFFECTS OF THIS SUBSTANCE. ======================= First Aid Measures ======================= First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN: IMMED FLUSH THORO W/LARGE AMOUNTS OF WATER. EYES: IMMED FLUSH THORO W/WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. GIVE A RTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. INGESTION: IF CONSCIOUS, DRINK WATER & INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:-49F,-45C Lower Limits:1.90% Upper Limits:36.00% Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL. Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL. Unusual Fire/Explosion Hazard:DANGEROUS FIRE & EXPLO HAZ. MAY FORM EXPLO PEROXIDES, ESPECIALLY WHEN HEATED. CLSD CONTRS MAY EXPLODE WHEN EXPOSED TO HEAT. VAP CAN TRAVEL DIST TO (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE PROT EQUIP LISTED UNDER CTL MEASURES SECTION. ELIMINATE ANY IGNIT SOURCES UNTIL AREA DETERMINED TO BE FREE FROM EXPLO/FIRE HAZ. CONTAIN RELEASE & ELIMINA TE ITS SOURCE, IF THIS CAN BE DONE W/OUT (SUP DAT) Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE IN COOL, DRY AREA AWAY FROM IGNIT SOURCES & OXIDIZERS. CHECK PEROXIDE CONTENT BEFORE HEATING MATL. Other Precautions:DO NOT BREATHE DUST/VAP. DO NOT GET IN EYES, ON SKIN/CLTHG. ELEC GROUND ALL EQUIP WHEN HNDLG THIS PROD. RETAINED RESIDUE MAY MAKE EMPTY CONTRS HAZ. USE CAUTION! PROT AGAINST PHYSICAL DMG & DIRECT SUNL IGHT. DO NOT TAKE INTERNALLY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH/MSHA APPRVD AIR-SUPP RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESP (NEG PRESS TYPE) UNDER SPECIFIED (ING 3) Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION. Protective Gloves:NITRILE OR EQUIVALENT GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS . Other Protective Equipment:EMER EYEWASH & DELUGE SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ: SOURCE & FLASH BACK. SPILL PROC: RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISP. WASTE DISP METH: SERVICE DEPARTMENT (609) 354-9200. THE FOLLOWING MFR SPILL-X ABSORB I S REC FOR THIS PROD: SX0863 SOLV SPILL TREATMENT KIT. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:95.0F,35.0C Melt/Freeze Pt:M.P/F.P Text:-189F,-123C Vapor Pres:442 @ 20C Vapor Density:2.6 Spec Gravity:0.71 (H*2O=1) Evaporation Rate & Reference:37.5 (BUTYL ACETATE=1) Solubility in Water:SOLUBLE Appearance and Odor:COLORLESS LIQUID WITH SWEET ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, ACETYL PEROXIDE, LIQUID AIR, BROMOAZIDE, CHLORINE. Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCE, LIGHT, AIR. EVAPORATING TO NEAR DRYNESS. Hazardous Decomposition Products:CARBON MONOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:COMPLY W/FED, STATE, & LOC REGS ON REPORTING RELEASES. REFER TO REG INFO FOR REPORTABLE QTY & OTHER REG DATA. MFR REC SPILL-X ABSORB AGENTS FOR VARIOUS TYPES OF SPILLS. ADDNL INFO ON SPILL-X PROD CAN BE PROVIDED THRU EM SCIENCE TECHNICAL (SUP DAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.