FISHER SCIENTIFIC -- SODIUM (DI) ETHYLENEDIAMINE TETRAACETA SO-S-221 -- 6810-00-300-5149
===================== Product Identification ===================== Product ID:SODIUM (DI) ETHYLENEDIAMINE TETRAACETA SO-S-221 MSDS Date:11/22/1994 FSC:6810 NIIN:00-300-5149 === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LN City:FAIR LAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100;800-424-9300(CHEMTREC) CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID, (ETHYLENEDINITRILO)TETRA-, DISODIUM SALT, DIHYDRATE; (SODIUM (DI) ETHYLENEDIAMINE TETRAACETATE). (ING 2) CAS:6381-92-6 RTECS #:AH4410000 Fraction by Wt: 0.4% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:ING 1: LD50: (ORAL, RAT) 2 G/KG RTECS #:9999999ZZ OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SODIUM HYDROXIDE (CERCLA) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: 0.049% OSHA PEL:2 MG/M3 ACGIH TLV:2 MG/M3, C EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:MAGNESIUM CHLORIDE, HEXAHYDRATE; (MAGNESIUM CHLORIDE) CAS:7791-18-6 RTECS #:OM2975000 Fraction by Wt: 0.01% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: 99.54% OSHA PEL:N/K ACGIH TLV:N/K Ingred Name:SUPDAT: THESE RATS ALSO SUFFERED FROM DIARR & PRIAPISM. A 60% MORTALITY OCCURRED IN IN THE 10% DIET GROUP & 20% (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: MORTALITY IN THE 5% GROUP. REPRO EFTS HAVE BEEN REPORTED IN ANIMAL STUDIES. ETHYLENEDIAMINETETRAACETIC (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: ACID, DISODIUM SALT TOXICITY: LOC EFTS-EYE IRRITANT. ACUTE TOXICITY LEVEL-MOD TOX BY INGEST. TARGET EFTS- (ING 9) RTECS #:9999999ZZ Ingred Name:ING 8:POISONING MAY AFFECT KIDNEYS. ADDNL DATA:PARENTERAL ADMIN OF EDTA OR ITS SALTS IN HIGH DOSES MAY CAUSE SEV(ING 10) RTECS #:9999999ZZ Ingred Name:ING 9: RENAL LESIONS & TUBULAR NECROSIS, INTERNAL HEMORRHAGE, LIFE-THREATENING HYPOCALCEMIA & DEATH. PRLNGD (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: PARENTERAL ADMIN MAY LEAD TO ELECTROLYTE IMBALANCE & CARDIAC ARRHYTHMIAS. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC:UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. INGEST: IF VOMIT OCCURS, (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: KEEP HEAD LOWER THAN HIPS TO HELP PVNT ASPIR. TREAT SYMP & SUPPORTIVELY. GET MED ATTN IF NEEDED. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL:NO SPECIFIC DATA AVAIL. INHAL OF DUSTS/MISTS OF EDTA SALTS MAY CAUSE MUC MEMB IRRIT W/SORE THROAT & COUGH. SKIN: NO SPECIFIC DATA AVAIL. EDTA SALTS MAY CAUSE IRRIT W/REDNESS & PAIN. EYES :CNTCT W/EDTA SALTS MAY CAUSE IRRIT W/REDNESS, PAIN & SOME TRANSIENT CORNEAL INJURY. INGEST:SOLNS OF (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ: SALTS OF EDTA ARE EXTREMELY IRRIT TO GI SYS. ALTHOUGH POORLY ABSORBED, IF SUFFICIENT AMTS ARE INGESTED SYSTEMIC TOX MAY RSLT. EDTA & ITS SALT MAY CHELATE LEAD, MAGNESIUM, ZINC & TRACE METALS IF PRESENT IN INTESTINE POSS CAUSING THEIR INCRD ABSORPTION & THEREBY INCR TOTAL BODY STORE OF THESE METALS. (SUPDAT) Medical Cond Aggravated by Exposure:PERSONS WITH RENAL OR HEART DISEASE; A HISTORY OF SEIZURES OR INTRACRANIAL LESIONS; POTASSIUM DEFICIENCY OR INSULIN-DEPENDENT DIABETES. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE FROM EXPOS AREA TO FRESH AIR IMMED. PERFORM ARTF RESP IF NEC. KEEP WARM & AT REST. TREAT SYMP & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE CONTAMD CLTHG & SHOES IMMED. WASH W/SOAP OR MILD DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (AT LEAST 15-20 MIN). GET MED ATTN IMMED. EYES: WASH IMMED W/LG AMTS OF WATER OR NORM SALINE, OCCAS LIFTING UPPER & LOWER LIDS (ING 12) ===================== Fire Fighting Measures ===================== Flash Point:NOT COMBUSTIBLE Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR REGULAR FOAM. FOR LARGER FIRES USE WATER SPRAY, FOG OR REGULAR FOAM. Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIPMENT . NO ACUTE HAZARD. MOVE CNTNR FROM FIRE AREA IF POSSIBLE. AVOID BREATHING VAPORS OR DUSTS; KEEP UPWIND. Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR FLAME. ================== Accidental Release Measures ================== Spill Release Procedures:OCCUPATIONAL SPILL: COVER WITH SODA ASH. SCOOP UP AND PLACE IN A SUITABLE CONTAINER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER. Other Precautions:NONE SPECIFIED BY MANUFACTURER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:HIGH LEVELS - NIOSH/MSHA APPROVED DUST, MIST AND FUME RESPIRATOR. Ventilation:PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION SYSTEM. Protective Gloves:IMPERVIOUS GLOVES . Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . PROTECTIVE CLOTHING NOT REQD. AVOID RPTD/PRLNGD CONTACT W/THIS SUBSTANCE. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health EFTS OF OVEREXP: CHRONIC: SKIN: RPTD/PRLNGD CNTCT W/EDTA SALTS MAY CAUSE MOD IRRIT & POSS MILD BURN. EYES: RPTD/PRLNGD CNTCT W/EDTA SALTS MAY CAUSE CONJ. INGEST: IN FEEDING STUDIES, RATS FED DIET OF 5 & 10% EDTA DISODIUM SALTS FOR UP TO 13WKS SHOWED DECRD FOOD CONSUMPTION & WT GAIN WHEN COMPARED TO CONTROLS. (ING 6) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C Vapor Pres:14 Spec Gravity:1.02 Evaporation Rate & Reference:>1 (ETHER =1) Solubility in Water:COMPLETE Appearance and Odor:COLORLESS LIQUID. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS (STRONG): FIRE AND EXPLOSION HAZARD. Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE TOXIC OXIDES OF NITROGEN, SODIUM AND CARBON. ==================== Disposal Considerations ==================== Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN STORING OR DISPOSING OF THIS SUBSTANCE. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.