PHIPPS PRODUCTS CORP. -- ETHYLENE GLYCOL,TECHNICAL-MIL-E-9500B -- 6810-00-006-4205
===================== Product Identification ===================== Product ID:ETHYLENE GLYCOL,TECHNICAL-MIL-E-9500B MSDS Date:08/24/1989 FSC:6810 NIIN:00-006-4205 === Responsible Party === Company Name:PHIPPS PRODUCTS CORP. Address:186 LINCOLN STREET SUITE 502 City:BOSTON State:MA ZIP:02111-2403 Country:US Info Phone Num:COMPANY OUT OF BUSINESS Emergency Phone Num:COMPANY OUT OF BUSINESS Preparer's Name:DGSC-SSH CAGE:86511 === Contractor Identification === Company Name:PHIPPS PRODUCTS CORP Address:186 LINCOLN ST SUITE 502 Box:City:BOSTON State:MA ZIP:02111-2403 Country:US Phone:OUT OF BUSINESS CAGE:86511 ============= Composition/Information on Ingredients ============= Ingred Name:ETHYLENE GLYCOL (SARA III) CAS:107-21-1 RTECS #:KW2975000 Fraction by Wt: <99.9% OSHA PEL:C 50 PPM ACGIH TLV:C 50 PPM,VAPOR; 9192 EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB Ingred Name:1,4-DIOXANE (DIETHYLENE DIOXIDE) (SARA III) CAS:123-91-1 RTECS #:JG8225000 Fraction by Wt: 0.0015% OSHA PEL:S, 100 PPM ACGIH TLV:S, 25 PPM; 9293 EPA Rpt Qty:100 LBS DOT Rpt Qty:100 LBS Ingred Name:ETHYLENE OXIDE (SARA III) CAS:75-21-8 RTECS #:KX2450000 Fraction by Wt: 0.0001% OSHA PEL:1 PPM; SEE 1910.1047 ACGIH TLV:1 PPM, A2; 9192 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT) IS 4G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES,SKIN,RESPIRATORY OR G.I.TRACTS;CNS EFFECTS LIKE HEADACHE,DIZZINESS,NAUSEA,VOMITING AND POSSIBLE UNCONSCIOUSNESS;FATAL IF INGESTED.CHRONIC:DRYING OF SKIN,DEFATTING OR DERMATITI S/ALLERGIC REACTION OR SENSITIZITON,LIVER AND KIDNEY DAMAGE,CNS DEPRESSION. Explanation of Carcinogenicity:ETHYLENE GLYCOL HAS SHOWN TO PRODUCE DOSE- RELATED TERATOGENIC EFFECTS IN RATS AND MICE WHEN GIVEN BY GAVAGE. Effects of Overexposure:CNS EFFECTS ARE HEADACHE,DIZZINESS,NAUSEA,VOMITING,POSSIBLE UNCONSCIOUSNESS.SKIN:DRYING,DERMATITIS. Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE. ======================= First Aid Measures ======================= First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING. GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOV E CONTAMINATED CLOTHING. WASH WITH SOAPAND WATER. IF IRRITATION PERSISTS, GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:241F,116C Lower Limits:3.2 Upper Limits:15.3 Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER FOG. Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE. Unusual Fire/Explosion Hazard:NONE. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTION;CONTAIN FREE MATERIAL IF POSSIBLE;USE SUITABLE INERT ABSORBENT MATERIAL AND RECOVER FOR PROPER DISPOSAL IN AN APPROVED CONTAINER. Neutralizing Agent:NOT APPLICABLE. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT CONTAINERS FROM PHYSICAL DAMAGE. Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE MIST. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC VAPROR/MIST IF ABOVE PEL/TLV OR SCBA IN AN ENCLOSED AREA. Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. Protective Gloves:NEOPRENE, NITRILE, OR NATURAL RUBBER. Eye Protection:SAFETY GOGGLES WITH FACE SHIELD Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER,WORK CLOTHING AND APRON AS REQUIRED. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR FOOTWEAR. Supplemental Safety and Health AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO NOT BREATHE VAPORS OR MISTS.DO NOT TAKE INTERNALLY. ================== Physical/Chemical Properties ================== HCC:V5 Boiling Pt:>197.2C, 387.F Melt/Freeze Pt:=-12.6C, 9.F Vapor Pres:0.08 Vapor Density:2.1 Spec Gravity:1.115 Evaporation Rate & Reference:0.01(N-BUTYL ACETATE = 1) Solubility in Water:100 %(COMPLETE) Appearance and Odor:COLORLESS LIQUID,MILD ODOR ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS,STRONG ACIDS,STRONG BASES AND MATERIAL REACTIVE WITH HYDROXYL COMPOUNDS. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND OTHER UNIDENTIFIED COMPONENTS. ==================== Disposal Considerations ==================== Waste Disposal Methods:CONSULT LOCAL AUTHORITIES.DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS. 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